Year: 2024 | Month: January | Volume: 11 | Issue: 1 | Pages: 195-209
DOI: https://doi.org/10.52403/ijrr.20240121
Review of Synthesis and Characterization of Cu (I) Complexes
Eishika1, Himani2, Ridhi3, Vanshika4
1,2,3,4(Department of Chemistry, Post Graduate Govt. College for Girls, Sec-11, Chandigarh, India)
Corresponding Author: Veneeta Anand
ABSTRACT
d-block metals show great promise in inorganic catalytic research. Particularly, copper, d9 metal has contributed to catalytic properties of its complexes. A series of copper complexes was synthesized and structurally characterized. The copper (I) complexes of this series were investigated in regard to their reactivity towards dioxygen using stopped-flow techniques. For most complexes no “oxygen adduct” complexes as intermediates could be detected. In this article, some complexes of Cu (I) have been included and the ligands on which work had been done are mentioned below:
1,5-bis(benzimidazole-2-yl)-3-thiapentane
Tridentate di-pyrazole -3,6-di-tert-butyl-carbazole (N, N, N-Pincer ligand)
Methyl isocyanate
N4Cu
Tris(pyrazolyl) hydroborate ligand
Scorpionate ligand
Phenanthroline
Tripodal amine ligands
Triazole derivatives
Keywords: BBES (1,5-bis(benzimidazole-2-yl)-3-thiapentane), MeIN (Methyl isocyanate), CuSCN (copper thiocyanate), PPh3(triphenyl phosphine), PCy3(tricyclohexyl phosphine), TptBuPh (tris[3-(p-tert-butylphenyl)], Tp (tris pyrazolyl hydroborate), Me4-p,3,3 (3,3-dimethylaminopropyl-(2-methylenpyridyl)-amine), Me2-pp3 (3-dimethylaminopropyl-bis(2-methylenpyridyl)-amine)
[PDF Full Text]